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Neutral complexes of first row transition metals bearing unbound thiocyanates and their assembly on metallic surfaces

Journal of the American Chemical Society, ISSN: 0002-7863, Vol: 128, Issue: 10, Page: 3179-3189
2006
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Article Description

A series of transition metal coordination complexes designed to assemble on gold surfaces was synthesized, their electronic structure and transitions analyzed, and their magnetic properties studied. By taking advantage of recently developed thiocyanate assembly protocols, these molecules were then assembled onto a gold surface, without the need for an inert atmosphere, to give a loosely packed monolayer. The assembled molecules exhibit properties similar to that of the bulk molecules, indicating little change in molecular structure outside of chemisorption. © 2006 American Chemical Society.

Bibliographic Details

Ciszek, Jacob W; Keane, Zachary K; Cheng, Long; Stewart, Michael P; Yu, Lam H; Natelson, Douglas; Tour, James M

American Chemical Society (ACS)

Chemical Engineering; Chemistry; Biochemistry, Genetics and Molecular Biology

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