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A propeller-like uranyl metallomesogen

Journal of the American Chemical Society, ISSN: 0002-7863, Vol: 127, Issue: 50, Page: 17602-17603
2005
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Article Description

Uranyl triflate forms with three imidazo[4,5-f]-1,10-phenanthroline ligands a propeller-like complex that exhibits a hexagonal columnar phase. The ligand is not liquid-crystalline, but a mesophase is induced upon complex formation with the uranyl salt. The thermal behavior has been investigated by polarizing optical microscopy and by high-temperature X-ray diffraction. A model of the stacking of the molecules in the mesophase is proposed. Copyright © 2005 American Chemical Society.

Bibliographic Details

Cardinaels, Thomas; Ramaekers, Jan; Guillon, Daniel; Donnio, Bertrand; Binnemans, Koen

American Chemical Society (ACS)

Chemical Engineering; Chemistry; Biochemistry, Genetics and Molecular Biology

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