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Control of the electrode-molecule interface for molecular devices

Journal of the American Chemical Society, ISSN: 0002-7863, Vol: 129, Issue: 18, Page: 5818-5819
2007
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Article Description

Using the monolayers of benzenethiol, benzeneselenol, and biphenyl ditelluride on a gold substrate, we investigated the stability of the Au-S, Au-Se, and Au-Te bonds and the charge injection barrier in their interfaces. The Au-S and Au-Se bonds were formed in a stable manner, while in the monolayer of biphenyl ditelluride, a tellurium oxide was generated. It was also found that the charge injection barrier was smaller in the Au-Se interface than in the Au-S interface, therefore leading us to indicate that the Au-Se interface was more appropriate for molecular devices than the Au-S or Au-Te interfaces. Copyright © 2007 American Chemical Society.

Bibliographic Details

Yokota, Kazumichi; Taniguchi, Masateru; Kawai, Tomoji

American Chemical Society (ACS)

Chemical Engineering; Chemistry; Biochemistry, Genetics and Molecular Biology

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