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Determining the enantioselectivity of chiral catalysts by mass spectrometric screening of their racemic forms

Journal of the American Chemical Society, ISSN: 0002-7863, Vol: 133, Issue: 13, Page: 4710-4713
2011
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Article Description

The enantioselectivity of a chiral catalyst can be determined from its racemic form by mass spectrometric screening of a nonequal mixture of two mass-labeled quasienantiomeric substrates. The presented method opens up new possibilities for evaluating catalyst structures that are not readily available in enantiomerically pure form. © 2011 American Chemical Society.

Bibliographic Details

Ebner, Christian; Müller, Constanze A; Markert, Christian; Pfaltz, Andreas

American Chemical Society (ACS)

Chemical Engineering; Chemistry; Biochemistry, Genetics and Molecular Biology

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