Ruthenium-catalyzed (2 + 2) intramolecular cycloaddition of allenenes
Journal of the American Chemical Society, ISSN: 0002-7863, Vol: 133, Issue: 20, Page: 7660-7663
2011
- 82Citations
- 35Captures
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Example: if you select the 1-year option for an article published in 2019 and a metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019. If you select the 3-year option for the same article published in 2019 and the metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019, 2018 and 2017.
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Metrics Details
- Citations82
- Citation Indexes82
- 82
- CrossRef80
- Captures35
- Readers35
- 35
Article Description
We report a ruthenium-catalyzed (2 + 2) intramolecular cycloaddition of allenes and alkenes. We have found that the use of the ruthenium complex RuHCl(PPr), which has previously gone unnoticed in catalytic applications, is crucial for the observed reactivity. The reaction proceeds under mild conditions and is fully diastereoselective, providing a practical entry to a variety of bicyclo[3.2.0]heptane skeletons featuring cyclobutane rings. © 2011 American Chemical Society.
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