A highly enantio- and diastereoselective molybdenum-catalyzed asymmetric allylic alkylation of cyanoesters
Journal of the American Chemical Society, ISSN: 0002-7863, Vol: 133, Issue: 21, Page: 8165-8167
2011
- 109Citations
- 58Captures
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Metrics Details
- Citations109
- Citation Indexes109
- 109
- CrossRef100
- Captures58
- Readers58
- 58
Article Description
An efficient molybdenum-catalyzed asymmetric allylic alkylation (Mo-AAA) of cyanoester nucleophiles is reported. A number of highly functionalized branched cyanoesters containing a quaternary carbon stereocenter with a vicinal tertiary stereocenter are obtained. This method generates a number of functionalized cyanoesters in excellent yield and chemoselectivity in good to excellent diastereoselectivity and enantioselectivity. © 2011 American Chemical Society.
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