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A highly enantio- and diastereoselective molybdenum-catalyzed asymmetric allylic alkylation of cyanoesters

Journal of the American Chemical Society, ISSN: 0002-7863, Vol: 133, Issue: 21, Page: 8165-8167
2011
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Article Description

An efficient molybdenum-catalyzed asymmetric allylic alkylation (Mo-AAA) of cyanoester nucleophiles is reported. A number of highly functionalized branched cyanoesters containing a quaternary carbon stereocenter with a vicinal tertiary stereocenter are obtained. This method generates a number of functionalized cyanoesters in excellent yield and chemoselectivity in good to excellent diastereoselectivity and enantioselectivity. © 2011 American Chemical Society.

Bibliographic Details

Barry M. Trost; John R. Miller; Christopher M. Hoffman Jr.

American Chemical Society (ACS)

Chemical Engineering; Chemistry; Biochemistry, Genetics and Molecular Biology

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