Poly(ionic liquid) complex with spontaneous micro-/mesoporosity: Template-free synthesis and application as catalyst support
Journal of the American Chemical Society, ISSN: 0002-7863, Vol: 134, Issue: 29, Page: 11852-11855
2012
- 178Citations
- 127Captures
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Metrics Details
- Citations178
- Citation Indexes178
- 178
- CrossRef165
- Captures127
- Readers127
- 127
Article Description
A facile, template-free synthetic route is reported toward poly(ionic liquid) complexes (PILCs) which for the first time exhibit stable micro-/mesoporous structure. This is accomplished via in situ ionic complexation between imidazolium-based PILs and poly(acrylic acid) in various alkaline organic solvents. The PILC can be highly loaded with copper salts and can be used as a catalytic support for effective aerobic oxidation of activated hydrocarbons under mild conditions. © 2012 American Chemical Society.
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