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Poly(ionic liquid) complex with spontaneous micro-/mesoporosity: Template-free synthesis and application as catalyst support

Journal of the American Chemical Society, ISSN: 0002-7863, Vol: 134, Issue: 29, Page: 11852-11855
2012
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Article Description

A facile, template-free synthetic route is reported toward poly(ionic liquid) complexes (PILCs) which for the first time exhibit stable micro-/mesoporous structure. This is accomplished via in situ ionic complexation between imidazolium-based PILs and poly(acrylic acid) in various alkaline organic solvents. The PILC can be highly loaded with copper salts and can be used as a catalytic support for effective aerobic oxidation of activated hydrocarbons under mild conditions. © 2012 American Chemical Society.

Bibliographic Details

Zhao, Qiang; Zhang, Pengfei; Antonietti, Markus; Yuan, Jiayin

American Chemical Society (ACS)

Chemical Engineering; Chemistry; Biochemistry, Genetics and Molecular Biology

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