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Highly chemoselective metal-free reduction of phosphine oxides to phosphines

Journal of the American Chemical Society, ISSN: 0002-7863, Vol: 134, Issue: 44, Page: 18325-18329
2012
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Article Description

Unprecedented chemoselective reductions of phosphine oxides to phosphines proceed smoothly in the presence of catalytic amounts of specific Brønsted acids. By utilizing inexpensive silanes, e.g., PMHS or (EtO) MeSiH, other reducible functional groups such as ketones, aldehydes, olefins, nitriles, and esters are well-tolerated under optimized conditions. © 2012 American Chemical Society.

Bibliographic Details

Li, Yuehui; Lu, Liang-Qiu; Das, Shoubhik; Pisiewicz, Sabine; Junge, Kathrin; Beller, Matthias

American Chemical Society (ACS)

Chemical Engineering; Chemistry; Biochemistry, Genetics and Molecular Biology

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