A polar copper-Boron One-Electron σ-bond
Journal of the American Chemical Society, ISSN: 0002-7863, Vol: 135, Issue: 10, Page: 3792-3795
2013
- 86Citations
- 114Captures
- 3Mentions
Metric Options: Counts1 Year3 YearSelecting the 1-year or 3-year option will change the metrics count to percentiles, illustrating how an article or review compares to other articles or reviews within the selected time period in the same journal. Selecting the 1-year option compares the metrics against other articles/reviews that were also published in the same calendar year. Selecting the 3-year option compares the metrics against other articles/reviews that were also published in the same calendar year plus the two years prior.
Example: if you select the 1-year option for an article published in 2019 and a metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019. If you select the 3-year option for the same article published in 2019 and the metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019, 2018 and 2017.
Citation Benchmarking is provided by Scopus and SciVal and is different from the metrics context provided by PlumX Metrics.
Example: if you select the 1-year option for an article published in 2019 and a metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019. If you select the 3-year option for the same article published in 2019 and the metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019, 2018 and 2017.
Citation Benchmarking is provided by Scopus and SciVal and is different from the metrics context provided by PlumX Metrics.
Metrics Details
- Citations86
- Citation Indexes86
- CrossRef86
- 84
- Captures114
- Readers114
- 114
- Mentions3
- News Mentions2
- News2
- References1
- Wikipedia1
Most Recent News
Carbon bond that uses only one electron seen for first time: ‘It will be in the textbooks’
Nature, Published online: 26 September 2024; doi:10.1038/d41586-024-03138-2 The fundamental discovery deepens scientists’ understanding of chemical bonding.
Article Description
Virtually all chemical bonds consist of one or several pairs of electrons shared by two atoms. Examples of σ-bonds made of a single electron delocalized over two neighboring atoms were until recently found only in gas-phase cations such as H and Li and in highly unstable species generated in solid matrices. Only in the past decade was bona fide one-electron bonding observed for molecules in fluid solution. Here we report the isolation and structural characterization of a thermally stable compound featuring a Cu-B one-electron bond, as well as its oxidized (nonbonded) and reduced (two-electrons-bonded) congeners. This triad provides an excellent opportunity to study the degree of σ-bonding in a metalloboratrane as a function of electron count. © 2013 American Chemical Society.
Bibliographic Details
American Chemical Society (ACS)
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