An FeF·0.5HO polytype: A microporous framework compound with intersecting tunnels for li and na batteries
Journal of the American Chemical Society, ISSN: 0002-7863, Vol: 135, Issue: 31, Page: 11425-11428
2013
- 180Citations
- 117Captures
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Example: if you select the 1-year option for an article published in 2019 and a metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019. If you select the 3-year option for the same article published in 2019 and the metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019, 2018 and 2017.
Citation Benchmarking is provided by Scopus and SciVal and is different from the metrics context provided by PlumX Metrics.
Metrics Details
- Citations180
- Citation Indexes180
- 180
- CrossRef155
- Captures117
- Readers117
- 117
Article Description
To improve the energy/power density of energy storage materials, numerous efforts have focused on the exploration of new structure prototypes, in particular metal-organic fameworks, Prussian blue analogues, open-framework oxides, and polyanion salts. Here we report a novel pyrochlore phase that appears to be useful as a high-capacity cathode for Li and Na batteries. It is an iron fluoride polymorph characterized by an intersecting tunnel structure, providing the space for accommodation and transport of Li and Na ions. It is prepared using hydrolyzable ionic liquids, which serve as reaction educts and structure-directing agents not only as far as the chemical structure is concerned but also in terms of morphology (shape, defect structure, electrode network structure). A capacity higher than 220 mA h g (for Li and Na storage) and a lifetime of at least 300 cycles (for Li storage) are demonstrated. © 2013 American Chemical Society.
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