Alkahest for VVI chalcogenides: Dissolution of nine bulk semiconductors in a diamine-dithiol solvent mixture
Journal of the American Chemical Society, ISSN: 1520-5126, Vol: 135, Issue: 42, Page: 15722-15725
2013
- 174Citations
- 184Captures
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Example: if you select the 1-year option for an article published in 2019 and a metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019. If you select the 3-year option for the same article published in 2019 and the metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019, 2018 and 2017.
Citation Benchmarking is provided by Scopus and SciVal and is different from the metrics context provided by PlumX Metrics.
Metrics Details
- Citations174
- Citation Indexes174
- 174
- CrossRef151
- Captures184
- Readers184
- 184
Article Description
The ability to solution deposit semiconductor films has received a great deal of recent attention as a way to potentially lower costs for many optoelectronic applications; however, most bulk semiconductors are insoluble in common solvents. Here we describe a novel and relatively nonhazardous binary solvent mixture comprised of 1,2-ethanedithiol and 1,2-ethylenediamine that possesses the remarkable ability to rapidly dissolve a series of nine bulk VVI chalcogenides (V = As, Sb, Bi; VI = S, Se, Te) at room temperature and atmospheric pressure. After solution deposition and low-temperature annealing, the chalcogenides can be fully recovered as good quality, highly crystalline thin films with negligible organic content, as demonstrated for SbSe and BiS. © 2013 American Chemical Society.
Bibliographic Details
American Chemical Society (ACS)
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