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Metal-organic proximity in a synthetic pocket

Journal of the American Chemical Society, ISSN: 0002-7863, Vol: 136, Issue: 8, Page: 2966-2969
2014
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Article Description

Proximity between a noninteractive organic substrate and a transition metal (trans-MCl(PEt); M = Pd or Pt) is achieved by their co-encapsulation within a synthetic cage, as revealed by X-ray crystallographic analysis and NOESY experiments. Through co-encapsulation with a Pd(II) complex, a terminal alkyne was activated within the cage to give a σ-alkynylpalladium complex. © 2014 American Chemical Society.

Bibliographic Details

Kohyama, Yuh; Murase, Takashi; Fujita, Makoto

American Chemical Society (ACS)

Chemical Engineering; Chemistry; Biochemistry, Genetics and Molecular Biology

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