Palladium(II)-catalyzed enantioselective C(sp)-H activation using a chiral hydroxamic acid ligand
Journal of the American Chemical Society, ISSN: 1520-5126, Vol: 136, Issue: 22, Page: 8138-8142
2014
- 220Citations
- 161Captures
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Example: if you select the 1-year option for an article published in 2019 and a metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019. If you select the 3-year option for the same article published in 2019 and the metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019, 2018 and 2017.
Citation Benchmarking is provided by Scopus and SciVal and is different from the metrics context provided by PlumX Metrics.
Metrics Details
- Citations220
- Citation Indexes220
- CrossRef220
- 220
- Captures161
- Readers161
- 161
Article Description
An enantioselective method for Pd(II)-catalyzed cross-coupling of methylene β-C(sp)-H bonds in cyclobutanecarboxylic acid derivatives with arylboron reagents is described. High yields and enantioselectivities were achieved through the development of chiral mono-N-protected α-amino-O- methylhydroxamic acid (MPAHA) ligands, which form a chiral complex with the Pd(II) center. This reaction provides an alternative approach to the enantioselective synthesis of cyclobutanecarboxylates containing α-chiral quaternary stereocenters. This new class of chiral catalysts also show promises for enantioselective β-C(sp)-H activation of acyclic amides. © 2014 American Chemical Society.
Bibliographic Details
American Chemical Society (ACS)
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