Palladium-catalyzed intramolecular direct arylation of benzoic acids by Tandem decarboxylation/C-H activation
Journal of the American Chemical Society, ISSN: 0002-7863, Vol: 131, Issue: 12, Page: 4194-4195
2009
- 376Citations
- 112Captures
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Metrics Details
- Citations376
- Citation Indexes376
- CrossRef376
- 373
- Captures112
- Readers112
- 112
Article Description
A novel protocol for the palladium-catalyzed intramolecular direct arylation of benzoic acids is reported, which combines decarboxylation and C-H activation into one efficient process. With the optimized catalyst system of palladium trifluoroacetate, silver carbonate, and the proper solvent mixture (5% DMSO/dioxane), dibenzofuran derivatives are formed in excellent yield and selectivity. © 2009 American Chemical Society.
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