Dynamic measurements of aqueous lanthanide triflate-catalyzed reactions using luminescence decay
Journal of the American Chemical Society, ISSN: 0002-7863, Vol: 131, Issue: 18, Page: 6342-6343
2009
- 32Citations
- 25Captures
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Metrics Details
- Citations32
- Citation Indexes32
- 32
- CrossRef27
- Captures25
- Readers25
- 25
Article Description
There is tremendous interest in water-compatible lanthanide triflate-based catalysts for carbon-carbon bond forming reactions; however, poor understanding of their aqueous mechanism severely limits the ability to increase the utility of these catalysts. Here, we report dynamic measurements of the water-coordination number of lanthanide triflate-based catalysts using luminescence-decay measurements in a range of aqueous systems. This unique characterization method is a reliable, convenient, and fast approach to analyze lanthanide-based catalysts in aqueous systems. Copyright © 2009 American Chemical Society.
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