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Enantioselective synthesis of (+)-cephalostatin 1

Journal of the American Chemical Society, ISSN: 0002-7863, Vol: 132, Issue: 1, Page: 275-280
2010
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Article Description

This Article describes an enantioselective synthesis of cephalostatin 1. Key steps of this synthesis are a unique methyl group selective allylic oxidation, directed C-H hydroxylation of a sterol at C12, Au(I)-catalyzed 5-endo-dig cyclization, and a kinetic spiroketalization. © 2010 American Chemical Society.

Bibliographic Details

Fortner, Kevin C; Kato, Darryl; Tanaka, Yoshiki; Shair, Matthew D

American Chemical Society (ACS)

Chemical Engineering; Chemistry; Biochemistry, Genetics and Molecular Biology

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