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p-Tolylsulfinyl Amides: Reagents for Facile Electrophilic Functionalization of Olefins

Journal of Organic Chemistry, ISSN: 0022-3263, Vol: 69, Issue: 7, Page: 2584-2587
2004
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A variety of olefins were found to react with sulfinyl amides in the presence of POCl to give β-chlorosulfides and β-hydroxysulfides in good yields. In the absence of nucleophiles, p-tolylsulfinyl amides were found to react with olefins with the formation of allylsulfoxides.

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