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Development of catalysts for the stereoselective hydrogenation of α,β-unsaturated ketones

Journal of Organic Chemistry, ISSN: 0022-3263, Vol: 77, Issue: 11, Page: 5139-5143
2012
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Iridium phosphinitoxazoline complexes were found to be new efficient catalysts for the asymmetric hydrogenation of arylated α,β- unsaturated ketones. Linear as well as cyclic substrates are hydrogenated with similar success, giving selectivities of up to 99.7% ee. © 2012 American Chemical Society.

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