Rapid and accurate estimation of densities of room-temperature ionic liquids and salts
Journal of Physical Chemistry A, ISSN: 1089-5639, Vol: 111, Issue: 8, Page: 1456-1461
2007
- 363Citations
- 152Captures
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Metrics Details
- Citations363
- Citation Indexes363
- 363
- CrossRef331
- Captures152
- Readers152
- 152
Article Description
Volume parameters for room-temperature ionic liquids (RTILs) and salts were developed. For 59 of the most common imidazolium, pyridinium, pyrrolidinium, tetralkylammonium, and phosphonium-based RTILs, the mean absolute deviation (MAD) of the densities is 0.007 g cm; for 35 imidazolium-based room-temperature salts, the MAD is 0.020 g cm; and for 150 energetic salts, the MAD is 0.035 g cm. The experimental density (Y) for an alkylated imidazolium or pyridinium-based room-temperature ionic liquid is approximately proportional to its calculated density (X) in the solid state: Y= 0.948X - 0.110 (correlation coefficient: R = 0.998, for BF PF, NTf-containing ionic liquids); Y = 0.934X - 0.070 (correlation coefficient: R = 0.999, for OTf, CFCO , N(CN)-containing ionic liquids). © 2007 American Chemical Society.
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