One more type of extrathermodynamic relationship
Journal of Physical Chemistry B, ISSN: 1520-6106, Vol: 111, Issue: 25, Page: 7331-7335
2007
- 6Citations
- 3Captures
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Example: if you select the 1-year option for an article published in 2019 and a metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019. If you select the 3-year option for the same article published in 2019 and the metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019, 2018 and 2017.
Citation Benchmarking is provided by Scopus and SciVal and is different from the metrics context provided by PlumX Metrics.
Metrics Details
- Citations6
- Citation Indexes6
- CrossRef6
- Captures3
- Readers3
Article Description
A new type of extrathermodynamic relationship is presented: ΔH = T[ΔS + R Δ (ln Ω)] + β, where Ω is the phase volume and β is a constant. This type of relationship holds for a series of systems in the case where δΔ (ln Ω) is changeable. The relation between this type of correlation and linear free-energy relationships is shown. An example of the specified correlation for energy parameters of excimers forming in different dipyrenylalkanes is demonstrated. © 2007 American Chemical Society.
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