Alloying in Cu/Pd nanoparticle catalysts
Journal of Physical Chemistry B, ISSN: 1520-6106, Vol: 102, Issue: 52, Page: 10680-10689
1998
- 103Citations
- 70Captures
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Article Description
In this paper we show a new application of the atomic layer epitaxy technique to prepare binary alloy nanoparticle catalysts on various supports. The technique is used to prepare Cu/Pd bimetallic catalysts on SiO2 and on y-Al2O3. The samples were characterized by means of transmission electron microscopy (TEM) and extended X-ray absorption fine structure (EXAFS) measurements. The EXAFS results show alloying in the Cu/Pd samples with a Cu-rich surface for the alumina-supported sample and random alloying for the silica-supported sample. From TEM and EXAFS measurements the particle sizes are determined to be in the range 20-60 A. © 1998 American Chemical Society.
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