Isotopic infrared absorption study of C, C, and C carbon cluster anions in Ar matrices
Journal of Physical Chemistry A, ISSN: 1089-5639, Vol: 102, Issue: 43, Page: 8300-8304
1998
- 18Citations
- 6Captures
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Article Description
The carbon cluster anions C, C, and C have been formed via a dual laser beam technique, trapped in Ar matrixes, and studied by infrared spectroscopy. C-Isotopic substitution combined with density functional (B3LYP/6-31G*) calculations of vibrational frequencies and intensities has led to the assignment of asymmetric stretching modes in the three anionic clusters. From the excellent fit of the calculated and experimental singly C-substituted cluster bands, a linear geometry for all three clusters has been determined.
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