Photopatterning of multilayer n -alkylsilane films
Langmuir, ISSN: 0743-7463, Vol: 28, Issue: 18, Page: 7129-7133
2012
- 9Citations
- 17Captures
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Article Description
Surface photopatterning of organosilane self-assembled monolayers (SAM) has received increasing attention since its introduction 20 years ago. Herein we report for the first time a cost-efficient soft photopatterning technique affording amplified 3D multilayer structures. The essential chemistry relies on a spatially controlled photoacid-catalyzed hydrolysis and polycondensation of n-alkyltrimethoxysilane precursors (n-C H Si(OCH ) ,). Amphiphilic siloxane species are photogenerated locally and are able to self-assemble spontaneously into a long-range-ordered lamellar mesostructure. © 2012 American Chemical Society.
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