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Layer-by-layer growth of oriented metal organic polymers on a functionalized organic surface

Langmuir, ISSN: 0743-7463, Vol: 23, Issue: 14, Page: 7440-7442
2007
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Article Description

A metal-organic coordination polymer based on benzenetricarboxylic acid ligands and Zn(II) ions was grown on a COOH-terminated organic surface in a stepwise fashion. The deposited films were characterized using a number of surface analysis techniques, including X-ray absorption spectroscopy and X-ray photoelectron spectroscopy. IR measurements show that the metal-organic coordination polymer grows in a layer-by-layer fashion and can be reversibly loaded with NH. The deposition is very selective and occurs only on COOH-terminated regions of an organic surface, as demonstrated by AFM measurements. © 2007 American Chemical Society.

Bibliographic Details

O. Shekhah; H. Wang; T. Strunskus; C. Wöll; D. Zacher; R. Fischer; P. Cyganik

American Chemical Society (ACS)

Materials Science; Physics and Astronomy; Chemistry

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