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A versatile method for grafting polymers on nanoparticles

Langmuir, ISSN: 0743-7463, Vol: 24, Issue: 10, Page: 5319-5323
2008
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Article Description

We report a simple and versatile method for grafting polymers on nanoparticles. A procedure was developed for the synthesis and subsequent functionalization of silica nanoparticles with a perfluorophenylazide. Polymers were then grafted by the photochemically induced insertion reactions of the perfluorophenylnitrene. Polystyrene, poly(4-vinylpyridine), and poly(2-ethyl-2-oxazoline) were successfully grafted on silica nanoparticles. Grafting density was studied with regard to polymer concentration and molecular weight. © 2008 American Chemical Society.

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