Versatile Chain Transfer Agents for Reversible Addition Fragmentation Chain Transfer (RAFT) Polymerization to Synthesize Functional Polymeric Architectures
Macromolecules, ISSN: 0024-9297, Vol: 37, Issue: 8, Page: 2709-2717
2004
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Article Description
We report the syntheses and uses of versatile chain transfer agents (CTAs) that produce well-controlled macromolecular architectures with specific chain-end functionalities, via reversible addition fragmentation chain transfer (RAFT) polymerization). Examples of architectures are given, including amphiphilic copolymers and block copolymers incorporating a biodegradable block. These CTAs are also used for the grafting of poly(styrene), poly(methyl methacrylate) and poly(methyl acrylate) from cotton.
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