Amphiphilic sun-shaped polymers by grafting macrocyclic copolyesters with PEO
Macromolecules, ISSN: 0024-9297, Vol: 41, Issue: 3, Page: 650-654
2008
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- 17Captures
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Article Description
An amphiphilic sun-shaped copolymer was successfully prepared by esterification of carboxylic acid terminated PEO with the pendent hydroxyl groups of high molecular weight (M = 28 000) cyclic PCL. The cyclic structure of the copolyester originally resulted from the polymerization initiation by a cyclic tin dialkoxide and was ultimately stabilized by the intramolecular cross-linking of a few unsaturated groups. © 2008 American Chemical Society.
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