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From brittle to pliant viscoelastic materials with solid state linear polyphosphonium-carboxylate assemblies

Macromolecules, ISSN: 0024-9297, Vol: 45, Issue: 5, Page: 2509-2513
2012
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Article Description

A polystyrenylphosphonium polymer was synthesized and complexed with various carboxylic acid derivatives to form new solid-state polyelectrolyte- surfactant assemblies. The properties of these ionic materials were highly dependent on the nature of the anion and included a brittle material, a rubbery ball that bounces, or a sticky fiber. The values for the equilibrium modulus, storage modulus, and loss modulus were dependent on the composition of the carboxylic acid and the number of electrostatic interactions. Small-angle X-ray scattering studies on the supramolecular assemblies confirmed a bilayer structure for two of the assemblies. © 2012 American Chemical Society.

Bibliographic Details

Godeau, Guilhem; Navailles, Laurence; Nallet, Frédéric; Lin, Xinrong; McIntosh, Thomas J; Grinstaff, Mark W

American Chemical Society (ACS)

Chemistry; Materials Science

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