Naphthoquinone-like polyketide isolated from Streptomyces sp. RI-77 and its predicted biosynthetic pathway
Journal of Natural Products, ISSN: 0163-3864, Vol: 74, Issue: 12, Page: 2588-2591
2011
- 9Citations
- 31Captures
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Metrics Details
- Citations9
- Citation Indexes9
- CrossRef8
- Captures31
- Readers31
- 31
Article Description
A novel naphthoquinone-like polyketide, JBIR-85 (1), with a unique skeleton and antioxidative activity was isolated from a culture of Streptomyces sp. RI-77. The planar structure of 1 was established on the basis of extensive NMR and MS analyses. The structure of 1 including the absolute configuration was established via X-ray crystallographic analysis. Since 1 exhibits a unique skeleton, we performed feeding experiments to reconfirm the structure and predict the biosynthetic pathway. © 2011 The American Chemical Society and American Society of Pharmacognosy.
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