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A linear multiporphyrinic [2]-rotaxane via amide bond formation

Organic Letters, ISSN: 1523-7060, Vol: 2, Issue: 20, Page: 3051-3054
2000
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Article Description

(matrix presented) A linear multiporphyrinic [2]-rotaxane has been synthesized using the transition metal-templating method for threading a gold(III)-incorporating macrocycle onto a rodlike, phenanthroline-derived chelate bearing carboxylate end groups. Stoppering has been performed by reacting the resulting prerotaxane with the amino derivative of a zinc tetraarylporphyrin under EDC-HOBt activation. A 34% yield has been realized for this one-pot, double amide bond formation.

Bibliographic Details

María Jesús Blanco; Jean Claude Chambron; Valérie Heitz; Jean Pierre Sauvage

American Chemical Society (ACS)

Biochemistry, Genetics and Molecular Biology; Chemistry

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