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Diastereoselective addition of allylzinc bromide to imines derived from (R)-phenylglycine amide

Organic Letters, ISSN: 1523-7060, Vol: 3, Issue: 24, Page: 3943-3946
2001
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Article Description

equation presented The highly diastereoselective addition of allylzinc bromide to imines derived from (R)-phenylglycine amide is reported. Homoallylamines with high enantiomeric purity are obtained from the adducts in three steps on removal of the chiral auxiliary by means of a nonreductive protocol. Removal of the auxiliary by hydrogenation leads to the saturated amines, also in high enantiomeric purity.

Bibliographic Details

Marcel Van Der Sluis; Richard M. Kellogg; Jan Dalmolen; Ben De Lange; Bernard Kaptein; Quirinus B. Broxterman

American Chemical Society (ACS)

Biochemistry, Genetics and Molecular Biology; Chemistry

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