Direct Vinylogous Mannich-Type Reactions via Ring Opening and Rearrangement of Vinyloxiranes
Organic Letters, ISSN: 1523-7060, Vol: 6, Issue: 3, Page: 345-347
2004
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- 21Captures
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Article Description
(Matrix presented) The first synthetic application of 2-methyl-2- vinyloxirane as a masked dienolate has been successfully demonstrated in the direct vinylogous Mannich-type reaction with an α-imino ester as an electrophile. The Mannich adduct was a useful intermediate en route to cis-5-substituted pipecolinic acid ethyl ester under simple hydrogenation conditions.
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