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Dialyzable carbosilane dendrimers as soluble supports for the functionalization of pyridine fragments via palladium-catalyzed coupling reactions

Organic Letters, ISSN: 1523-7060, Vol: 7, Issue: 3, Page: 363-366
2005
  • 28
    Citations
  • 0
    Usage
  • 11
    Captures
  • 0
    Mentions
  • 0
    Social Media
Metric Options:   Counts1 Year3 Year

Metrics Details

  • Citations
    28
    • Citation Indexes
      28
  • Captures
    11

Article Description

(Chemical Equation Presented) The use of carbosilane (CS) dendrimers as soluble supports in liquid phase organic synthesis (LPOS) is described. Control of the three key steps is perfectly achieved by covalently binding a pyridine fragment to the soluble support, modifying it via coupling reactions, and releasing it at the end. Nanofiltration (dialysis) allows facile purification of the supported molecules after each step.

Bibliographic Details

Jérôme Le Nôtre; Judith J. Firet; Leo A. J. M. Sliedregt; Bart J. van Steen; Gerard van Koten; Robertus J. M. Klein Gebbink

American Chemical Society (ACS)

Biochemistry, Genetics and Molecular Biology; Chemistry

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