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Reaction of unstabilized iodonium ylides with organoboranes

Organic Letters, ISSN: 1523-7060, Vol: 6, Issue: 9, Page: 1505-1508
2004
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Article Description

Exposure of monocarbonyl iodonium ylides, generated by the ester exchange of (Z)-(2-acetoxyvinyl)-λ-iodanes with EtOLi, to organoboranes results in a 1,2-shift of a carbon ligand from boron to the ylide carbons, which probably generates hitherto uncharacterized α-boryl ketones.

Bibliographic Details

Ochiai, Masahito; Tuchimoto, Yoshimi; Higashiura, Nobuyuki

American Chemical Society (ACS)

Biochemistry, Genetics and Molecular Biology; Chemistry

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