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Simplifying pyridoxal: Practical methods for amino acid dynamic kinetic resolution

Organic Letters, ISSN: 1523-7060, Vol: 12, Issue: 9, Page: 1916-1919
2010
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Article Description

Figure presented Metal complexes of picolinaldehyde are identified as low-cost and environmentally benign catalysts, providing high reaction rates and turnovers for the racemization of amino acids. These pyridoxal surrogates demonstrate activity toward a variety of amino acid esters. Applications to chemoenzymatic dynamic kinetic resolutions provide access to amino acids in high yields and with excellent enantioselectivities, demonstrating their compatibility with protease-mediated transformations. © 2010 American Chemical Society.

Bibliographic Details

Felten, Albert E; Zhu, Gangguo; Aron, Zachary D

American Chemical Society (ACS)

Biochemistry, Genetics and Molecular Biology; Chemistry

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