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Total synthesis of Oxazolomycin a

Organic Letters, ISSN: 1523-7060, Vol: 13, Issue: 19, Page: 5398-5401
2011
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Article Description

The first total synthesis of oxazolomycin A, a structurally novel oxazole polyene γ-lactam/β-lactone antibiotic, is described. Key features include the stereocontrolled construction of the right-hand heterocyclic core bytaking advantage of an In(III)-catalyzed Conia-ene type cyclization and theasymmetric synthesis of the left-hand segment starting with a Cinchona alkaloid-catalyzed cyclocondensation of an aldehyde with an acid chloride. © 2011 American ChemicalSociety.

Bibliographic Details

Eto, Kohei; Yoshino, Madoka; Takahashi, Keisuke; Ishihara, Jun; Hatakeyama, Susumi

American Chemical Society (ACS)

Biochemistry, Genetics and Molecular Biology; Chemistry

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