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Manganese porphyrin catalyzed cycloisomerization of enynes

Organic Letters, ISSN: 1523-7060, Vol: 14, Issue: 12, Page: 3008-3011
2012
  • 31
    Citations
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  • 10
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Metrics Details

  • Citations
    31
    • Citation Indexes
      31
  • Captures
    10

Article Description

Cycloisomerization of 1,6-enynes to five- or six-membered ring systems is successfully carried out in the presence of a cationic manganese(III) catalyst. The use of a structurally rigid tetradentate porphyrin as the equatorial ligand and a weakly coordinating axial ligand is the key to bringing out the catalytic reactivity of manganese for the reaction. The axial ligand of the catalyst has a marked effect on the product and selectively aids the formation of five- or six-membered cyclic products. © 2012 American Chemical Society.

Bibliographic Details

Ozawa, Takuya; Kurahashi, Takuya; Matsubara, Seijiro

American Chemical Society (ACS)

Biochemistry, Genetics and Molecular Biology; Chemistry

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