A catalytic borylation/dehalogenation route to o -fluoro arylboronates
Organic Letters, ISSN: 1523-7052, Vol: 16, Issue: 23, Page: 6072-6075
2014
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Article Description
A two-step Ir-catalyzed borylation/Pd-catalyzed dehalogenation sequence allows for the net synthesis of fluoroarenes where the boronic ester is ortho to fluorine. Key elements of this approach include the use of a halogen para to the fluorine to block meta Ir-catalyzed borylation and the chemoselective Pd-catalyzed dehalogenation by KF activated polymethylhydrosiloxane (PMHS).
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