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A catalytic borylation/dehalogenation route to o -fluoro arylboronates

Organic Letters, ISSN: 1523-7052, Vol: 16, Issue: 23, Page: 6072-6075
2014
  • 26
    Citations
  • 0
    Usage
  • 25
    Captures
  • 0
    Mentions
  • 0
    Social Media
Metric Options:   Counts1 Year3 Year

Metrics Details

  • Citations
    26
    • Citation Indexes
      26
  • Captures
    25

Article Description

A two-step Ir-catalyzed borylation/Pd-catalyzed dehalogenation sequence allows for the net synthesis of fluoroarenes where the boronic ester is ortho to fluorine. Key elements of this approach include the use of a halogen para to the fluorine to block meta Ir-catalyzed borylation and the chemoselective Pd-catalyzed dehalogenation by KF activated polymethylhydrosiloxane (PMHS).

Bibliographic Details

Chathurika R. K. Jayasundara; Jason M. Unold; Jossian Oppenheimer; Milton R. Smith III; Robert E. Maleczka Jr.

American Chemical Society (ACS)

Biochemistry, Genetics and Molecular Biology; Chemistry

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