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Copper-mediated α-trifluoromethylation of N -phenylcinnamamides coupled with dearomatization: Access to trifluoromethylated 1-azaspiro[4.5]decanes

Organic Letters, ISSN: 1523-7052, Vol: 16, Issue: 22, Page: 5914-5917
2014
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Article Description

Copper-mediated intramolecular trifluoromethylation of N-phenylcinnamamides coupled with cyclization and dearomatization was used to construct various trifluoromethylated 1-azaspiro[4.5]decanes in moderate to high yields and with excellent regioselectivity and diastereoselectivity.

Bibliographic Details

Han, Guifang; Wang, Qiang; Liu, Yuxiu; Wang, Qingmin

American Chemical Society (ACS)

Biochemistry, Genetics and Molecular Biology; Chemistry

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