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Enantioselective synthesis of 3,3-disubstituted oxindoles through pd-catalyzed cyanoamidation

Organic Letters, ISSN: 1523-7060, Vol: 10, Issue: 15, Page: 3303-3306
2008
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Article Description

(Chemical Equation Presented) The first enantioselective cyanoamidation of olefins provides quick access to a variety of 3,3-disubstituted oxindoles. The combination of Pd(dba)2, an optically active phosphoramidite, and N,N-dimethylpropylene urea (DMPU) in decalin were found to be the best conditions. © 2008 American Chemical Society.

Bibliographic Details

Yasui, Yoshizumi; Kamisaki, Haruhi; Takemoto, Yoshiji

American Chemical Society (ACS)

Biochemistry, Genetics and Molecular Biology; Chemistry

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