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Gold-catalyzed cycloisomerization of N-propargylindole-2-carboxamides: Application toward the synthesis of lavendamycin analogues

Organic Letters, ISSN: 1523-7060, Vol: 10, Issue: 16, Page: 3631-3634
2008
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Article Description

(Chemical Equation Presented) A series of N-propargylindole-2-carboxamides were found to undergo a AuCl-catalyzed cycloisomerization to give β-carbolinones in high yield. The corresponding β-chlorocarboline derivative was prepared and used for Pd(0)-catalyzed cross-coupling chemistry directed toward the synthesis of lavendamycin analogues. © 2008 American Chemical Society.

Bibliographic Details

England, Dylan B; Padwa, Albert

American Chemical Society (ACS)

Biochemistry, Genetics and Molecular Biology; Chemistry

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