EPR characterization of diamagnetic and magnetic organic soft materials using nitroxide spin probe techniques
Electron Paramagnetic Resonance, ISSN: 1465-1955, Vol: 23, Issue: 1, Page: 1-21
2013
- 16Citations
- 11Captures
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Book Chapter Description
This review article summarizes the recent advances in the EPR studies of the molecular orientation and magnetic properties in the various rod-like liquid crystalline (LC) phases of the second-generation of organic nitroxide radical materials in the bulk state or in a surface-stabilized LC cell, compared with the conventional EPR studies using classical organic nitroxide spin probes. Noteworthy is the first observation and characterization of a sort of spin glass-like ferromagnetic interactions ( J>0) induced by weak magnetic fields in the various LC phases of the second-generation of organic nitroxide radical materials. This unique magnetic property has been referred to as positive "magneto-LC effects". The utility of such novel LC nitroxide radical materials as the EPR spin probes is also presented. © The Royal Society of Chemistry 2013.
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=84878333184&origin=inward; http://dx.doi.org/10.1039/9781849734837-00001; https://books.rsc.org/books/book/1775/chapter/1820952/EPR-characterization-of-diamagnetic-and-magnetic; https://dx.doi.org/10.1039/9781849734837-00001; https://pubs.rsc.org/en/content/chapter/9781849734837-00001/978-1-84973-483-7
Royal Society of Chemistry (RSC)
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