A dodecanuclear copper(ii) cage self-assembled from six dicopper building units
Dalton Transactions, ISSN: 1477-9226, Vol: 43, Issue: 10, Page: 4076-4085
2014
- 14Citations
- 19Captures
Metric Options: CountsSelecting the 1-year or 3-year option will change the metrics count to percentiles, illustrating how an article or review compares to other articles or reviews within the selected time period in the same journal. Selecting the 1-year option compares the metrics against other articles/reviews that were also published in the same calendar year. Selecting the 3-year option compares the metrics against other articles/reviews that were also published in the same calendar year plus the two years prior.
Example: if you select the 1-year option for an article published in 2019 and a metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019. If you select the 3-year option for the same article published in 2019 and the metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019, 2018 and 2017.
Citation Benchmarking is provided by Scopus and SciVal and is different from the metrics context provided by PlumX Metrics.
Example: if you select the 1-year option for an article published in 2019 and a metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019. If you select the 3-year option for the same article published in 2019 and the metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019, 2018 and 2017.
Citation Benchmarking is provided by Scopus and SciVal and is different from the metrics context provided by PlumX Metrics.
Article Description
Reaction of the dinucleating phenol-based ligand, Hbpmp (2,6-bis-[(3-hydroxy-propylimino)-methyl]-4-methyl-phenol), with Cu ions in the presence of a hybrid base (NEt and NaN) necessary for the in situ generation of required numbers of hydroxido ions, results in the formation of a novel NO capped and HO supported {Cu} coordination complex {Cu (μ-OH)(μ-Hbpmp) (μ-NO)}(NO) (OH)·2HO·2MeOH (1). When the components are combined in right proportions (metal:ligand:NEt :NaN = 2:1:3:2) in MeOH, twelve Cu ions assemble in a cuboctahedral geometry, containing six square and eight triangular faces around a considerable void space. Six of the eight [Cu] triangular faces are bound by the six Hbpmp ligands with six free pendant propanol arms around the central hexagonal plane. X-ray structure determination indicates new geometrical features for the core formation and reveals the face-capping potential of the Hbpmp ligand for the growth of a cuboctahedral coordination cage with the support of anions like HO and NO. The experimentally observed (J/k = -173 K) strong antiferromagnetic coupling within the Cu complex has been justified by the DFT calculations. © 2014 The Royal Society of Chemistry.
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=84893932832&origin=inward; http://dx.doi.org/10.1039/c3dt53144a; http://www.ncbi.nlm.nih.gov/pubmed/24457598; https://xlink.rsc.org/?DOI=C3DT53144A; http://xlink.rsc.org/?DOI=C3DT53144A; http://pubs.rsc.org/en/content/articlepdf/2014/DT/C3DT53144A; https://dx.doi.org/10.1039/c3dt53144a; https://pubs.rsc.org/en/content/articlelanding/2014/dt/c3dt53144a
Royal Society of Chemistry (RSC)
Provide Feedback
Have ideas for a new metric? Would you like to see something else here?Let us know