PlumX Metrics
Embed PlumX Metrics

Reactivity of a: Trans -[H-MoMo-H] unit towards alkenes and alkynes: Bimetallic migratory insertion, H-elimination and other reactions

Chemical Communications, ISSN: 1364-548X, Vol: 54, Issue: 66, Page: 9186-9189
2018
  • 12
    Citations
  • 0
    Usage
  • 10
    Captures
  • 0
    Mentions
  • 0
    Social Media
Metric Options:   Counts1 Year3 Year

Metrics Details

Article Description

Complex [Mo(H){μ-HC(NDipp)}(THF)], (1·THF), reacts with CH and PhCHCH to afford hydrido-hydrocarbyl and bis(hydrocarbyl) derivatives of the MoMo bond. Reversible migratory insertion and β-hydrogen elimination, as well as reductive elimination and other reactions, have been uncovered. PhCCH behaves instead as a Brönsted-Lowry acid towards the strongly basic Mo-H bonds of 1·THF.

Bibliographic Details

Provide Feedback

Have ideas for a new metric? Would you like to see something else here?Let us know