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Intramolecular cycloadditions of N-alkenoyl aryl azides

Journal of the Chemical Society. Perkin Transactions 1, ISSN: 1364-5463, Vol: 1, Issue: 15, Page: 1816-1819
2001
  • 17
    Citations
  • 0
    Usage
  • 2
    Captures
  • 0
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Metric Options:   Counts1 Year3 Year

Metrics Details

  • Citations
    17
    • Citation Indexes
      17
  • Captures
    2

Article Description

Depending upon the reaction conditions, intramolecular cycloadditions of variously substituted N-alkenoyl aryl azides 4 give the [1,2,3]triazolobenzodiazepine 5, bridgehead aziridines 6 or imines 7. The dipolarophilic activity of the C&z.dbd;N double bond of the latter compounds is also exploited in the synthesis of [1,2,4]triazolobenzodiazepines 10 by means of nitrilimine cycloadditions. © 2001 The Royal Society of Chemistry.

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