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Selective head-to-tail recognition in hydrazide-based molecular duplex strands induced by spectator secondary electrostatic interactions

Organic and Biomolecular Chemistry, ISSN: 1477-0520, Vol: 6, Issue: 22, Page: 4198-4203
2008
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Article Description

Due to spectator secondary electrostatic interactions, nonsymmetric mono-Boc-mono-acetyl terminated hydrazide-based oligomers displayed a head-to-tail dimerization mode, which was evidenced by H NMR, and 2D NOESY experiments. Dynamic behavior of the molecular duplex strands was also explored by variable temperature H NMR experiments. © 2008 The Royal Society of Chemistry.

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