Regio- and stereo-selective synthesis of aryl 2-deoxy-C-glycopyranosides by palladium-catalyzed Heck coupling reactions of glycals and aryl iodides
Organic and Biomolecular Chemistry, ISSN: 1477-0520, Vol: 7, Issue: 18, Page: 3855-3861
2009
- 71Citations
- 20Captures
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Example: if you select the 1-year option for an article published in 2019 and a metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019. If you select the 3-year option for the same article published in 2019 and the metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019, 2018 and 2017.
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Metrics Details
- Citations71
- Citation Indexes71
- 71
- CrossRef65
- Captures20
- Readers20
- 20
Article Description
The Heck coupling of aryl iodides with pyranoid glycals using a catalytic amount of Pd(OAc) to form pyranoid aryl C-glycosides has been achieved. The reaction takes place smoothly in the presence of Ag CO and Cu(OAc) (or DMSO) in acetonitrile. This arylation process, which occurs in a highly regio- and stereo-selective manner, provides a simple, mild, and efficient approach to the synthesis of aryl 2-deoxy-C-glycopyranosides. © 2009 The Royal Society of Chemistry.
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=69549105967&origin=inward; http://dx.doi.org/10.1039/b909248j; http://www.ncbi.nlm.nih.gov/pubmed/19707693; https://xlink.rsc.org/?DOI=b909248j; https://dx.doi.org/10.1039/b909248j; https://pubs.rsc.org/en/content/articlelanding/2009/ob/b909248j
Royal Society of Chemistry (RSC)
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