Cyanogen isocyanate (NC-NCO) revisited: Thermal and chemical reactivity of a hydrogen-free precursor to C-N-(O) polymers
Journal of Materials Chemistry, ISSN: 0959-9428, Vol: 20, Issue: 1, Page: 110-116
2010
- 10Citations
- 11Captures
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Article Description
The first inorganic polyisocyanate, (NC-NCO), has been prepared and investigated. By polyaddition (polymerisation) of the reactive monomer cyanogen isocyanate (NC-NCO) at low temperatures, the moisture-sensitive polymer was obtained as a phase pure solid. Using several analytical techniques (UV, IR, NMR, MS, DSC, TGA), the formation and the principal connectivity patterns of the hydrogen-free amorphous inorganic network have been settled. From the experimental results, a close structural relation to the organic "nylons" was deduced. Upon thermal impact, this inorganic macromolecule behaves like a typical thermosetting material. Exposing polymeric CNO to a temperature between 400 and 500 °C leads to quantitative removal of oxygen in the form of CO. Depolymerisation and fragmentation at higher temperatures resulted in a virtually complete mass loss due to release of gaseous species. Some preliminary results concerning the high-pressure transformation towards a crystalline "CN O" (carbon oxynitride) are also given. © 2010 The Royal Society of Chemistry.
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=77949555076&origin=inward; http://dx.doi.org/10.1039/b914380g; http://xlink.rsc.org/?DOI=B914380G; http://pubs.rsc.org/en/content/articlepdf/2010/JM/B914380G; https://xlink.rsc.org/?DOI=B914380G; https://dx.doi.org/10.1039/b914380g; https://pubs.rsc.org/en/content/articlelanding/2010/jm/b914380g
Royal Society of Chemistry (RSC)
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