Sticky complexes: Carboxylic acid-functionalized N-phenylpyridin-2- ylmethanimine ligands as anchoring domains for copper and ruthenium dye-sensitized solar cells
Dalton Transactions, ISSN: 1477-9226, Vol: 39, Issue: 15, Page: 3585-3594
2010
- 53Citations
- 41Captures
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Example: if you select the 1-year option for an article published in 2019 and a metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019. If you select the 3-year option for the same article published in 2019 and the metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019, 2018 and 2017.
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Metrics Details
- Citations53
- Citation Indexes53
- 53
- CrossRef49
- Captures41
- Readers41
- 41
Article Description
Four members of a series of N-phenylpyridin-2-ylmethanimine ligands (L) decorated with carboxylic acid functionalities have been prepared. The ligand design allows a copper(i) complex [CuL] to bind to a TiO surface through the simultaneous use of two carboxylate anchoring domains. Complexes of the type [CuL][PF], [CuL(NCMe)][PF] and [Ru(bpy)L][PF ] have been synthesized and characterized by H and C NMR and electronic absorption spectroscopies, mass spectrometry and, for four of the complexes, single crystal X-ray diffraction. Dye-sensitized solar cells (DSCs) have been fabricated using the new complexes and the performances of the dyes assessed. The copper(i) complexes show good surface coverage and tuning of the electrolyte and the electronic properties of the ligands is now required to enhance the efficiencies of the DSCs. © 2010 The Royal Society of Chemistry.
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=77950243382&origin=inward; http://dx.doi.org/10.1039/b925623g; http://www.ncbi.nlm.nih.gov/pubmed/20354612; https://xlink.rsc.org/?DOI=b925623g; https://dx.doi.org/10.1039/b925623g; https://pubs.rsc.org/en/content/articlelanding/2010/DT/b925623g
Royal Society of Chemistry (RSC)
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