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Development of 5-silylethynyl-1,3-dioxolan-4-one as a new prochiral template for asymmetric phase-transfer catalysis

Chemical Communications, ISSN: 1359-7345, Vol: 46, Issue: 40, Page: 7593-7595
2010
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Phase-transfer catalyzed asymmetric alkylation and Michael addition of 5-silylalkynyl-1,3-dioxolan-4-one were developed as a novel strategy to provide highly modular tertiary α-alkyl-α-hydroxy acids bearing an alkyne moiety. © 2010 The Royal Society of Chemistry.

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